Superheater Tubes

Superheater tubes are pressure-containing tubes installed in a boiler superheater. They carry steam after the evaporation stage and absorb additional heat from the boiler gas path, raising the steam temperature above saturation before it reaches the turbine or process system.

Superheater tubes operate at high temperature and pressure for long periods. Material selection therefore requires consideration of tube metal temperature, steam pressure, oxidation, creep, thermal cycling and the applicable boiler design code.

Product Specifications

ItemDescription
ProductSeamless boiler superheater tubes
Material familiesMolybdenum steel, chromium-molybdenum steel, chromium-molybdenum-tungsten steel and austenitic stainless steel
Representative grades15MoG, 20MoG, T11, T22, T24, T91, T23, T92, T122, TP304H, TP321H and TP347H
Product standardsGB/T 5310; ASTM A209/A213 or corresponding ASME SA specifications, as applicable to the grade
Manufacturing routeHot-finished or cold-finished seamless tubes
Delivery conditionHeat treatment and surface condition according to the selected grade and standard
DimensionsOutside diameter × wall thickness × length
Principal applicationsPrimary, secondary and final superheater sections, as specified by the design

The representative grades belong to different standards and are not interchangeable. The purchase specification should identify the exact grade, product standard and standard edition.

Material Families and Grade Selection

Material familyRepresentative gradesSelection considerations
Molybdenum steel15MoG, 20MoGUsed where the design calls for carbon-molybdenum steel properties
Chromium-molybdenum steel15CrMoG, 12Cr1MoVG, T11, T22, T24 and T91Provides alloyed elevated-temperature strength for selected superheater zones
Chromium-molybdenum-tungsten steelT23, T92, T911 and T122Used where the specified alloy design and heat treatment suit demanding service conditions
Austenitic stainless steelTP304H, TP321H, TP347H, S30432 and TP310HCbNUsed where the design requires austenitic high-temperature strength and oxidation resistance

The handbook identifies these material families for superheater and reheater applications. Actual grade selection must be based on the design data and approved material specification.

Representative Mechanical Properties

The following values are historical reference values listed in the supplied boiler tube handbook.

GradeMinimum tensile strength, MPaMinimum yield strength, MPaMinimum elongation, %
T9158541520
T9262044020
T2351040020
T12262040020
TP304H51520535
S3043259023535
TP310HCbN65529530

Data basis: Baosteel Boiler Tube & Pipe handbook, printed in June 2007. The table is a historical comparison and is not a complete acceptance specification. Final mechanical properties, hardness, test conditions and heat-treatment requirements follow the standard edition and purchase specification stated in the order.

Room-temperature tensile properties do not establish an allowable service temperature. High-temperature design requires the applicable allowable stresses, creep data, oxidation behavior and expected operating life.

Superheater Sections and Heat Transfer

Superheaters are commonly arranged in multiple banks or sections. Steam conditions and gas temperature change along the gas path, so tube metal temperature is not necessarily the same in every section.

The design may use primary, platen or final superheater sections. Tube spacing, gas velocity, soot deposits, steam-side flow and heat flux all affect the thermal duty. The selected material and wall thickness must suit the hottest and most highly stressed locations identified by the boiler design.

Fouling and ash deposits can increase tube metal temperature and alter gas-side heat transfer. Operation, soot blowing, water chemistry and inspection are therefore part of the tube service requirements.

Heat Treatment and Fabrication

Heat treatment establishes the microstructure and mechanical properties required by the selected grade. The required process varies between molybdenum, chromium-molybdenum, chromium-molybdenum-tungsten and austenitic stainless steels.

Superheater tubes may be bent or fabricated into assemblies. Bending, welding and post-weld heat treatment must follow qualified procedures and the applicable construction code. Procedure qualification should address preheat, interpass temperature, consumables, heat input and any required post-weld treatment.

T91, T92 and other creep-resistant ferritic grades require controlled fabrication and heat-treatment practices. Austenitic stainless steel grades have different thermal expansion and thermal conductivity from ferritic alloy steels; mixed-material connections should be designed accordingly.

Superheater Tubes and Reheater Tubes

FeatureSuperheater tubesReheater tubes
Steam sourceSteam leaving the evaporation or primary superheater systemSteam returning from an intermediate turbine stage
Main dutyRaise steam above the saturation temperatureReheat returned steam before the next turbine stage
Key material factorsTube metal temperature, steam pressure, oxidation and creepTemperature, pressure, thermal cycling, oxidation and creep
Typical material familiesMo steel, Cr-Mo steel, Cr-Mo-W steel and austenitic stainless steelMo steel, Cr-Mo steel, Cr-Mo-W steel and austenitic stainless steel

The same grade is not automatically suitable for both locations. The superheater or reheater design, temperature profile and pressure conditions determine the required product.

Manufacturing and Inspection

Seamless tubes are produced by piercing solid billets followed by hot working or cold finishing. Required heat treatment, straightening, surface finishing and final inspection depend on the product standard and order.

Depending on the specification, inspection may include:

  • Heat and product chemical analysis.
  • Tensile, yield and elongation testing.
  • Hardness testing and heat-treatment records.
  • Outside diameter, wall thickness, length and straightness checks.
  • Internal and external surface inspection.
  • Flattening, flaring or other specified technological tests.
  • Hydrostatic testing and/or specified nondestructive examination.
  • Additional impact, metallographic or grain-size tests where required by the grade or project.

Inspection documents should identify the product standard, grade, heat number, dimensions, delivery condition and applicable test results. Traceability should be maintained through bending, welding and final assembly.

Ordering Information

For a quotation, specify:

  • Grade: required Mo, Cr-Mo, Cr-Mo-W or austenitic stainless steel grade.
  • Standard: GB/T 5310, ASTM A209/A213, ASME SA-209/SA-213 or another specified standard and edition.
  • Dimensions: outside diameter, wall thickness basis and length.
  • Quantity: number of tubes, total length or weight.
  • Delivery condition: heat treatment and surface condition.
  • Application: primary, secondary or final superheater service.
  • Fabrication: bend drawings, weld requirements and post-weld heat treatment where applicable.
  • Inspection: certificate requirements, nondestructive examination and additional tests.

If an ASTM or ASME pipe grade such as P91 or P92 is required for a steam line, specify it as a pipe product under its applicable standard. T91 or T92 tube designations do not automatically establish equivalence with P91 or P92 pipes.